Train Heartnet is the infamous gunman 'Black Cat', a cold-blooded assassin who works for the organization known as 'Chronos', bearing the mark XIII on his body. Most of his life was surrounded by violence, so Train is quiet, asocial and uncaring. However his life changes as he encounters the mysterious Sweeper (bounty hunter), Saya. Her unique way of living interested Train but tragedy occurs, resulting in Train changing the way he has lived towards the life of a Sweeper with newfound friends Sven and Eve.

Asta and Yuno were abandoned together at the same church and have been inseparable since. As children, they promised that they would compete against each other to see who would become the next Emperor Magus. However, as they grew up, some differences between them became plain. Yuno was a genius with magic, with amazing power and control, while Asta could not use magic at all, and tried to make up for his lack by training physically. When they received their Grimoires at age 15, Yuno got a spectacular book with a four-leaf clover (most people receive a three-leaf-clover), while Asta received nothing at all. However, when Yuno was threatened, the truth about Asta's power was revealed, he received a five-leaf clover Grimoire, a "black clover"! Now the two friends are heading out in the world, both seeking the same goal!

Asta and Yuno were abandoned together at the same church and have been inseparable since. As children, they promised that they would compete against each other to see who would become the next Emperor Magus. However, as they grew up, some differences between them became plain. Yuno was a genius with magic, with amazing power and control, while Asta could not use magic at all, and tried to make up for his lack by training physically. When they received their Grimoires at age 15, Yuno got a spectacular book with a four-leaf clover (most people receive a three-leaf-clover), while Asta received nothing at all. However, when Yuno was threatened, the truth about Asta's power was revealed, he received a five-leaf clover Grimoire, a "black clover"! Now the two friends are heading out in the world, both seeking the same goal!

Asta is a young boy who dreams of becoming the greatest mage in the kingdom. He only has one problem, he can't use magic. Luckily for Asta, he receives the incredibly rare five-leaf clover grimoire that gives him the power of anti-magic. Even though he can't use magic, he plans to become the Wizard King.

The special episode features the captains of the different squads plus Asta and Yuno participating in a quiz show.

The special episode features the captains of the different squads plus Asta and Yuno participating in a quiz show.

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Living in a ninja residence tucked away in a corner of a futuristic city is Rikka, the eldest daughter of a Ninja clan, who looks up to her father—a researcher—very much. Carrying on with her life normally, Rikka's home came suddenly under attack one day. Driven into a corner, what would she do to overcome this crisis? Rip darkness to pieces and become "BLACK"!

Living in a ninja residence tucked away in a corner of a futuristic city is Rikka, the eldest daughter of a Ninja clan, who looks up to her father—a researcher—very much. Carrying on with her life normally, Rikka's home came suddenly under attack one day. Driven into a corner, what would she do to overcome this crisis? Rip darkness to pieces and become "BLACK"!

High school student Ibuki Keita has been haunted by misfortune for as long as he can remember. For no apparent reason, everyone around him dies tragically. Ultimately, he refuses to become too close to anyone, even his childhood friend Akane. This leaves Keita alone in a life full of misery and disgrace. While eating at his favorite ramen shop one evening, Keita meets a strange young girl named Kuro. Possessing abilities that surpass that of a normal human being, Kuro classifies herself as a Mototsumitama. She explains to Keita about “Terra”, a life-energy force split between three identical looking people; a global phenomenon dubbed the “Doppeliner System”. As a Mototsumitama, Kuro guards the “Coexistence Equilibrium”, the beings that protect the flow of Terra around the world. Keita refuses to believe her story, until he is caught up in the crossfire of this hidden world. On the verge of death, he makes a contract with Kuro, unbeknownst to its true meaning. Now he is bound to Kuro, and must be with her at all times. Could Keita's misfortune possibly get any greater?

Oji Tanaka has a wife, a child and a mundane job as a salary man in Tokyo’s modern society. But life wasn’t dull for him to begin with; 15 years ago, he was known as “Gabriel”, leader of a short-lived heavy metal band called Black Heaven. Oji’s life gets a sudden change in direction when he is invited by a mysterious blonde woman named Layla to pic… more Oji Tanaka has a wife, a child and a mundane job as a salary man in Tokyo’s modern society. But life wasn’t dull for him to begin with; 15 years ago, he was known as “Gabriel”, leader of a short-lived heavy metal band called Black Heaven. Oji’s life gets a sudden change in direction when he is invited by a mysterious blonde woman named Layla to pick up his Gibson Flying V and once again display his “legendary” guitar skills, not knowing that his music generates power for a massive weapon in an intergalactic war.